BLOGS

Significant Li plating capacity from Si anode. a, Li discharge profile in a battery of Li/graphite–Li_5.5PS_4.5Cl_1.5 (LPSCl1.5)–LGPS–LPSCl1.5–SiG at current density 0.2 mA cm^–2 at room temperature. Note that SiG was made by mixing Si and graphite in one composite layer. Inset shows the schematic illustration of stages 1–3 based on SEM and EDS mapping, which illustrate the unique Li–Si anode evolution in solid-state batteries observed experimentally in Figs. 1 and 2. b, FIB–SEM images of the SiG anode at different discharge states (i), (ii), and (iii) corresponding to points 1–3 in a, respectively. c, SEM–EDS mapping of (i), (ii), and (iii), corresponding to SEM images in b, where carbon signal (C) is derived from graphite, oxygen (O) and nitrogen (N) signals are from Li metal reaction with air and fluorine (F) is from the PTFE binder. d, Discharge profile of battery with cell construction Li-1M LiPF6 in EC/DMC–SiG. Schematics illustrate typical Si anode evolution in liquid-electrolyte batteries. e, FIB–SEM image (i) of SiG anode following discharge in the liquid-electrolyte battery shown in d; zoomed-in image (ii). Credit: Nature Materials (2024). DOI: 10.1038/s41563-023-01722-x

Topics: Applied Physics, Battery, Chemistry, Climate Change, Electrical Engineering, Mechanical Engineering

Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) have developed a new lithium metal battery that can be charged and discharged at least 6,000 times—more than any other pouch battery cell—and can be recharged in a matter of minutes.

The research not only describes a new way to make solid-state batteries with a lithium metal anode but also offers a new understanding of the materials used for these potentially revolutionary batteries.

The research is published in Nature Materials.

"Lithium metal anode batteries are considered the holy grail of batteries because they have ten times the capacity of commercial graphite anodes and could drastically increase the driving distance of electric vehicles," said Xin Li, Associate Professor of Materials Science at SEAS and senior author of the paper. "Our research is an important step toward more practical solid-state batteries for industrial and commercial applications."

One of the biggest challenges in the design of these batteries is the formation of dendrites on the surface of the anode. These structures grow like roots into the electrolyte and pierce the barrier separating the anode and cathode, causing the battery to short or even catch fire.

These dendrites form when lithium ions move from the cathode to the anode during charging, attaching to the surface of the anode in a process called plating. Plating on the anode creates an uneven, non-homogeneous surface, like plaque on teeth, and allows dendrites to take root. When discharged, that plaque-like coating needs to be stripped from the anode, and when plating is uneven, the stripping process can be slow and result in potholes that induce even more uneven plating in the next charge.

Solid-state battery design charges in minutes and lasts for thousands of cycles, Leah Burrows, Harvard John A. Paulson School of Engineering and Applied Sciences, Tech Xplore

Illustration of a UCLA-developed solid-state thermal transistor using an electric field to control heat movement. Credit: H-Lab/UCLA

Topics: Applied Physics, Battery, Chemistry, Electrical Engineering, Energy, Thermodynamics

A new thermal transistor can control heat as precisely as an electrical transistor can control electricity.

From smartphones to supercomputers, electronics have a heat problem. Modern computer chips suffer from microscopic “hotspots” with power density levels that exceed those of rocket nozzles and even approach that of the sun’s surface. Because of this, more than half the total electricity burned at U.S. data centers isn’t used for computing but for cooling. Many promising new technologies—such as 3-D-stacked chips and renewable energy systems—are blocked from reaching their full potential by errant heat that diminishes a device’s performance, reliability, and longevity.

“Heat is very challenging to manage,” says Yongjie Hu, a physicist and mechanical engineer at the University of California, Los Angeles. “Controlling heat flow has long been a dream for physicists and engineers, yet it’s remained elusive.”

But Hu and his colleagues may have found a solution. As reported last November in Science, his team has developed a new type of transistor that can precisely control heat flow by taking advantage of the basic chemistry of atomic bonding at the single-molecule level. These “thermal transistors” will likely be a central component of future circuits and will work in tandem with electrical transistors. The novel device is already affordable, scalable, and compatible with current industrial manufacturing practices, Hu says, and it could soon be incorporated into the production of lithium-ion batteries, combustion engines, semiconductor systems (such as computer chips), and more.

Scientists Finally Invent Heat-Controlling Circuitry That Keeps Electronics Cool, Rachel Newur, Scientific American

Electric field- and pressure-assisted fast sintering to control graphene alignment in thick composite electrodes for boosting lithium storage performance. Credit: Hongtao Sun, Penn State

Topics: Battery, Energy, Graphene, Green Tech, Lithium, Materials Science, Nanomaterials

The demand for high-performance batteries, especially for use in electric vehicles, is surging as the world shifts its energy consumption to a more electric-powered system, reducing reliance on fossil fuels and prioritizing climate remediation efforts. To improve battery performance and production, Penn State researchers and collaborators have developed a new fabrication approach that could make for more efficient batteries that maintain energy and power levels.

The improved method for fabricating battery electrodes may lead to high-performance batteries that would enable more energy-efficient electric vehicles, as well as such benefits as enhancing power grid storage, according to Hongtao Sun. Sun is an assistant professor of industrial and manufacturing engineering at Penn State and the co-corresponding author of the study, which was published in and featured on the front cover of Carbon.

"With current batteries, we want them to enable us to drive a car for longer distances, and we want to charge the car in maybe five minutes, 10 minutes, comparable to the time it takes to fill up for gas," Sun said. "In our work, we considered how we can achieve this by making the electrodes and battery cells more compact, with a higher percentage of active components and a lower percentage of passive components."

If an electric car maker wants to improve the driving distance of their vehicles, they add more battery cells, numbering in the thousands. The smaller and lighter, the better, according to Sun.

"The solution for longer driving distances for an electric vehicle is just to add compact batteries, but with denser and thicker electrodes," Sun said, explaining that such electrodes could better connect and power the battery's components, making them more active. "Although this approach may slightly reduce battery performance per electrode weight, it significantly enhances the vehicle's overall performance by reducing the battery package's weight and the energy required to move the electric vehicle."

Thicker, denser, better: New electrodes may hold the key to advanced batteries, Jamie Oberdick, Pennsylvania State University, techxplore.

Mick Fleetwood's Maui Restaurant destroyed in Maui fire. Allison Rapp, Ultimate Classic Rock

Topics: Battery, Chemistry, Civics, Civilization, Climate Change, Democracy, Existentialism

The Herculoids were a Hanna-Barbara cartoon that only ran for two seasons, from 1967 to 1969. From ages five to seven, I didn't demand much from my Saturday morning viewing pleasure: good guys, bad guys, action, good guys pummel bad guys, in this case, casting them off the planet. We landed on the Moon in their last year of air (it's a shame that history is now controversial). Dr. King and Robert Kennedy were assassinated In Medias Res. My understanding of Physics and STEM came much later.

Zandor, Tara, and Domo were the human protagonists defending planet "Amzot" (the writers threw spaghetti at the wall on this name). In a tepid reboot, they called it Quasar, a little more astrophysical but nonetheless kooky. They had a laser ray dragon (Zot), a rock ape (Igo), and a ten-legged rhino/triceratops hybrid that shot energy rocks from his snout (Tondro, the Terrific, because, yeah). Gloop and Gleep were human-sized, protoplasmic creatures called "the formless, fearless wonders," with eyes, and Gleep, was somehow the "son" of Gloop, without genitalia or gender (go with the bit?). The humans also shot energy rocks from slingshots at the foes too dumb to leave Zandor and his jungle planet alone. If the rocks were made of Lithium, they shouldn't have lasted too long: one of its properties is its volatility in oxygenated atmospheres.

In 1967, I would have been five years old and not too demanding of my visual entertainment on Saturday Morning Cartoons, as this old form pastime was called.

Taking a few courses in Physics drives a probing question and observation:

Where were the flocks of laser ray dragons, the congress of rock apes, the herds of rhino/triceratops hybrids, and what marshy bog did the "formless, fearless wonders" ascend from? It seemed Zot, Igo, Tondro, Gloop, and Gleep were the only ones of their kind.

In "Sarko: The Arkman," Sarko kidnaps Domo, Igo, and Tondro for his "collection" on another planet. Zandor rides Zot with Gloop to ANOTHER PLANET without the need of a spaceship, escape velocity, pressurized spacesuits, protection from radiation, or the friction of reentry to Sarko's world. Even if the planet was in the same orbital plane as Amzot, it didn't appear to take him long, and he wasn't bruised by a single meteor during the trip nor tanned from radiation burns (or dead). Gleep clones five copies of himself to protect Tara then turns up in a scene making himself a pillow on Sarko's world to catch Domo. Zot flew escort to Sarko's ship on the way back to Amzot again, with no loss of life. Did you follow all that?

Five-year-olds don't need Physics lessons, just a simple plot, a lot of action, and taking care of "evil-doers" before you play outside after Saturday cartoons.

It's magical thinking, but not a way to run human society.

"The human understanding is no dry light but receives an infusion from the will and affections; whence proceed sciences which may be called 'sciences as one would.' For what a man had rather were true, he more readily believes. Therefore, he rejects difficult things from impatience of research; sober things because they narrow hope; the deeper things of nature, from superstition; the light of experience, from arrogance and pride; things not commonly believed, out of the deference to the opinion of the vulgar. Numberless, in short, are the ways, and sometimes imperceptible, in which the affections color and infect the understanding."

Sir Francis Bacon, NOVUM ORGANON (1620)

Maui is a dystopian hellscape. It is now the deadliest wildfire in American history: until the next one. Reuters reports the cause of the fire is unknown, but 85% of all wildfires are caused by humans, as is the anthropogenic climate disruption that helped light the match. Hurricane Dora energized the spread, fanning the flames across the island that was experiencing a drought. Part of Maui's problem is prior to the predictions of climate scientists coming true in recent real-time, Maui never had to prepare for drought conditions or massive wildfires. Did I mention the island chain is surrounded by the Pacific Ocean?

Maui was the Capitol of the old kingdom of Hawaii before colonization. It was a tourist attraction and the seat of culture. Maui is the place where the Hula dance and the Samoan language were reconstituted and practiced. A 150-year-old banyan tree burned in the flames. It will survive IF the roots survived the savage flames.

"Some 271 structures were destroyed or damaged, the Honolulu Star-Advertiser said, citing official reports from the U.S. Civil Air Patrol and Maui Fire Department." Reuters

There is a throughline from Hurricane Katrina in Louisiana and Hurricane Dora in Maui. That throughline is climate change, gestated into the climate crisis, birthed into climate catastrophe. In eighteen years, we have shuffled, obfuscated, and kicked the can down the road right into our children's and grandchildren's future. We have allowed political operators and lobbyists for the fossil fuels industry to quote their "science as one would": "It's summer." "There is no climate change." "It's a (fill in the blank) hoax." "How can there be global warming if New York is blanketed in snow?"

The tobacco and fossil fuels industry used the same researchers and same lawyers to sway public opinion and sell their products. It is a myopic concentration on quarterly profits, not looking at the damage to the planet beneath them going forward. If Adam Smith's capitalism is our "salvation," there should be market-based solutions to ensure a functional civilization as corporations pursue profits and bought and paid-for politicians pursue policies that sustain both commerce and civilization.

Otherwise, their vulgar opinions have not offered solutions nor modeled societal collapse.

The Guardian reported from the National Academy of Science that more than 50% of life is in the soil beneath us. Life on Earth may survive our own hubris. It likely won't be intelligent or anything resembling human civilization.

Cartoon Network Physics is only good for five-year-olds on Saturday morning cartoons. There are no laser dragons, rock apes, rhino/triceratops-hybrids, and energy rocks to deploy to our rescue. It fails humanity in the long term. "Sciences as one would" has led us to this precipice. "Sciences as one acknowledges" will lead us away from it.

Note: The blog will resume Monday - Friday postings on August 21st (traveling for work).

Positive (+): LiMO₂ <--> Li_1-xMO

Negative (-): xLi⁺ + xe^- + C <--> Li_xC

M = transition metal

NANO 761: Introduction to Nano Energy, Lecture 4 - Lithium Ion Battery, Cathode to Anode, Spring 2018, JSNN

Topics: Battery, Climate Change, Green Tech, History, Nobel Laureate, Nobel Prize

John B. Goodenough, a professor at The University of Texas at Austin who is known around the world for the development of the lithium-ion battery, died Sunday at the age of 100. Goodenough was a dedicated public servant, a sought-after mentor, and a brilliant yet humble inventor.

His discovery led to the wireless revolution and put electronic devices in the hands of people worldwide. In 2019, Goodenough made national and international headlines after being awarded the Nobel Prize in chemistry for his battery work, an award many of his fans considered a long time coming, especially as he became the oldest person to receive a Nobel Prize.

“John’s legacy as a brilliant scientist is immeasurable — his discoveries improved the lives of billions of people around the world,” said UT Austin President Jay Hartzell. “He was a leader at the cutting edge of scientific research throughout the many decades of his career, and he never ceased searching for innovative energy-storage solutions. John’s work and commitment to our mission are the ultimate reflection of our aspiration as Longhorns — that what starts here changes the world — and he will be greatly missed among our UT community.”

UT Mourns Lithium-Ion Battery Inventor and Nobel Prize Recipient John Goodenough, UT News

Until the announcement of his selection as a Nobel laureate, Dr. Goodenough was relatively unknown beyond scientific and academic circles and the commercial titans who exploited his work. He achieved his laboratory breakthrough in 1980 at the University of Oxford, where he created a battery that has populated the planet with smartphones, laptop, and tablet computers, lifesaving medical devices like cardiac defibrillators, and clean, quiet plug-in vehicles, including many Teslas, that can be driven on long trips, lessen the impact of climate change and might someday replace gasoline-powered cars and trucks.

Like most modern technological advances, the powerful, lightweight, rechargeable lithium-ion battery is a product of incremental insights by scientists, lab technicians, and commercial interests over decades. But for those familiar with the battery’s story, Dr. Goodenough’s contribution is regarded as the crucial link in its development, a linchpin of chemistry, physics, and engineering on a molecular scale.

John B. Goodenough, 100, Dies; Nobel-Winning Creator of the Lithium-Ion Battery, Robert D. McFadden, New York Times

Before I met Professor Steve Wienberg, I had read my cousin Wilbur's copy of "The First Three Minutes." Little did I know that he would autograph it for me or that I would meet him, along with his former student (and my friend, Dr. Mark G. Raizen), at the National Society of Black Physicists in the fall of 2011 in Austin, Texas.

I never met John B. Goodenough, but I did study his theories in a class on battery nanomaterials at my graduate school. "Engineering on a molecular scale" is essentially what I studied in Nanoengineering, as batteries will only store charges longer and get better at the nanomaterials level. This is the way we will make the transition from fossil fuels to cleaner, more income-equitable options.

Ph.D. seemed so far away until the Hooding Ceremony. A few things about the tributes struck and moved me deeply:

He and his wife had no children, but Dr. Goodenough was enthusiastic about teaching, mentoring, and giving back. UT said he often donated any honorarium to the university.

He was from a home that, from the NY Times, was neglectful to him and indifferent.

He suffered from dyslexia and overcame it to achieve a Ph.D. in 1952 and a Nobel Prize at 97 in 2019. Everyone has their struggles, but for the love of science, he overcame them without excuses. A HUGE part of obtaining a degree in a STEM field is pure grit. Some of us quit too early from our dreams or debase our abilities before we even try.

The modern age we take for granted is possible because of humble spirits in laboratories, coding software, at dry erase boards full of equations who pushed a little further than any of their self-doubts. We are fortunate they pressed forward.

Nanos gigantum humeris insidentes - First recorded by John of Salisbury in the twelfth century and attributed to Bernard of Chartres. Also commonly known by the letters of Isaac Newton: "If I have seen further, it is by standing on the shoulders of giants."

John B. Goodenough in 2017. Two years later, when he was 97 and still active in research at the University of Texas at Austin, he became the oldest Nobel Prize winner in history. Credit...Kayana Szymczak for The New York Times

The new composition for fluorine-containing electrolytes promises to maintain high battery charging performance for future electric vehicles even at sub-zero temperatures. (Image by Shutterstock.)

Topics: Battery, Chemistry, Climate Change, Global Warming, Lithium, Materials Science

Scientists developed a new and safer electrolyte for lithium-ion batteries that work as well in sub-zero conditions as it does at room temperature.

Many owners of electric vehicles worry about how effective their batteries will be in very cold weather. Now new battery chemistry may have solved that problem.

In current lithium-ion batteries, the main problem lies in the liquid electrolyte. This key battery component transfers charge-carrying particles called ions between the battery’s two electrodes, causing the battery to charge and discharge. But the liquid begins to freeze at sub-zero temperatures. This condition severely limits the effectiveness of charging electric vehicles in cold regions and seasons.

To address that problem, a team of scientists from the U.S. Department of Energy’s (DOE) Argonne and Lawrence Berkeley national laboratories developed a fluorine-containing electrolyte that performs well even in sub-zero temperatures.

“Our research thus demonstrated how to tailor the atomic structure of electrolyte solvents to design new electrolytes for sub-zero temperatures.” — John Zhang, Argonne group leader.

“Our team not only found an antifreeze electrolyte whose charging performance does not decline at minus 4 degrees Fahrenheit, but we also discovered, at the atomic level, what makes it so effective,” said Zhengcheng ​“John” Zhang, a senior chemist and group leader in Argonne’s Chemical Sciences and Engineering division.

This low-temperature electrolyte shows promise of working for batteries in electric vehicles, as well as in energy storage for electric grids and consumer electronics like computers and phones.

An electric vehicle battery for all seasons, Joseph E. Harmon, Argonne National Labs

The new self-powered thermoelectric generator device uses an ultra-broadband solar absorber (UBSA) to capture sunlight, which heats the generator. Simultaneously, another component called a planar radiative cooling emitter (RCE) cools part of the device by releasing heat. Credit: Haoyuan Cai, Jimei University

Topics: Alternate Energy, Battery, Chemistry, Energy, Materials Science, Thermodynamics

Researchers have developed a new thermoelectric generator (TEG) that can continuously generate electricity using heat from the sun and a radiative element that releases heat into the air. Because it works during the day or night and in cloudy conditions, the new self-powered TEG could provide a reliable power source for small electronic devices such as outdoor sensors.

"Traditional power sources like batteries are limited in capacity and require regular replacement or recharging, which can be inconvenient and unsustainable," said research team leader Jing Liu from Jimei University in China. "Our new TEG design could offer a sustainable and continuous energy solution for small devices, addressing the constraints of traditional power sources like batteries."

TEGs are solid-state devices that use temperature differences to generate electricity without moving parts. In the journal Optics Express, Liu and a multi-institutional team of researchers describe and demonstrate a new TEG that can simultaneously generate the heat and cold necessary to create a temperature difference large enough to generate electricity even when the sun isn't out. The passive power source is made of components that can easily be manufactured.

"The unique design of our self-powered thermoelectric generator allows it to work continuously, no matter the weather," said Liu. "With further development, our TEG has the potential to impact a wide range of applications, from remote sensors to wearable electronics, promoting a more sustainable and eco-friendly approach to powering our daily lives."

New passive device continuously generates electricity during the day or night, Optica/Tech Explore

Photo: Getty Images

Topics: Battery, Chemistry, Climate Change, Economics, Global Warming

Welcome back to The Green Era, a weekly newsletter bringing you the news and trends in the world of sustainability. Click subscribe above to be notified of future editions.

The shift to renewable energy has caused consternation over the fate of workers in the fossil fuel industry. Those same concerns are hitting the automotive sector as U.S. demand for electric vehicles grows.

EVs require not just new assembly lines and parts but also factories to build the batteries that power them. The president of one of the biggest unions called the transition the largest in the industry’s history.

The automotive sector and its workers are not new to factory closures. The Great Recession brought the big three automakers to their knees, forcing the federal government to bail them out, leaving cities like Detroit and large swaths of the midwest with car workers out of a job.

This time could be different. Many factories are being converted and are investing in retraining their workers. The batteries and charging infrastructure required present another opportunity. Ford, General Motors, and Volkswagen are all building new battery manufacturing plants or expanding existing ones in Tennessee.

The EV transition is changing workers’ skills and state economies, Jordyn Dahl, LinkedIn

Divine light The Dean of Gloucester Cathedral, Stephen Lake, blesses the cathedral’s solar panels after the solar-energy firm MyPower installed them in November 2016. The array of PV panels generates just over 25% of the building’s electricity. (Courtesy: MyPower)

Topics: Alternate Energy, Applied Physics, Battery, Chemistry, Economics, Solar Power

With energy bills on the rise, plenty of people are interested in ditching the fossil fuels currently used to heat most UK homes. The question is how to make it happen, as Margaret Harris explains.

Deep beneath the flagstones of the medieval Bath Abbey church, a modern marvel with an ancient twist is silently making its presence felt. Completed in March 2021, the abbey’s heating system combines underfloor pipes with heat exchangers located seven meters below the surface. There, a drain built nearly 2000 years ago carries 1.1 million liters of 40 °C water every day from a natural hot spring into a complex of ancient Roman baths.

By tapping into this flow of warm water, the system provides enough energy to heat not only the abbey but also an adjacent row of Georgian cottages used for offices. No wonder the abbey’s rector praised it as “a sustainable solution for heating our beautiful historic church.”

But that wasn’t all. Once efforts to decarbonize the abbey’s heating were underway, officials in the £19.4m Bath Abbey Footprint project turned their attention to the building’s electricity. Like most churches, the abbey runs from east to west, giving its roof an extensive south-facing aspect. At the UK’s northerly latitudes, such roofs are bathed in sunlight for much of the day, making them ideal for solar photovoltaic (PV) panels. Gloucester Cathedral – an hour’s drive north of Bath – has already taken advantage of this favorable orientation, becoming – in 2016 – the UK’s first major ancient cathedral to have solar panels installed on its roof.

To find out if a similar set-up might be suitable at Bath Abbey, the Footprint project worked with Ph.D. students in the University of Bath-led Centre for Doctoral Training (CDT) in New and Sustainable Photovoltaics. In a feasibility study published in Energy Science & Engineering (2022 10 892), the students calculated that a well-designed array of PV panels could supply 35.7% of the abbey’s electricity, plus 4.6% that could be sold back to the grid on days when a surplus was generated. The array would pay for itself within about 13 years and generate a total profit of £139,000 ± £12,000 over its 25-year lifetime.

Home, green home: scientific solutions for cutting carbon and (maybe) saving money, Margaret Harris, Physics World

Panel A shows how the native SEI on Li metal is passivating to nitrogen, which means that no reactivity with Li metal is possible. Panel B shows that a proton donor like Ethanol will disrupt the SEI passivation and enable Li metal to react with nitrogen species. Panel C describes 3 potential mechanisms through which the proton donor can disrupt the SEI passivation. Credit: Steinberg et al.

Topics: Applied Physics, Battery, Chemistry, Climate Change, Environment

Ammonia (NH₃), the chemical compound made of nitrogen and hydrogen, currently has many valuable uses, for instance, serving as a crop fertilizer, purifying agent, and refrigerant gas. In recent years, scientists have been exploring its potential as an energy carrier to reduce global carbon emissions and help tackle global warming.

Ammonia is produced via the Haber-Bosch process, a carbon-producing industrial chemical reaction that converts nitrogen and hydrogen into NH3. As this process is known to contribute heavily to global carbon emissions, electrifying ammonia synthesis would benefit our planet.

One of the most promising strategies for electrically synthesizing ammonia at ambient conditions is using lithium metal. However, some aspects of these processes, including the properties and role of lithium's passivation layer, known as the solid electrolyte interphase (SEI), remain poorly understood.

Researchers at the Massachusetts Institute of Technology (MIT), the University of California- Los Angeles (UCLA), and the California Institute of Technology have recently conducted a study closely examining the reactivity of lithium and its SEI, as this could enhance lithium-based pathways to electrically synthesize ammonia. Their observations, published in Nature Energy, were collected using a state-of-the-art imaging method known as cryogenic transmission electron microscopy.

Using cryogenic electron microscopy to study the lithium SEI during electrocatalysis, Ingrid Fadelli, Phys.org

The effective mass of the electrons can be derived from the curvature around the maxima of the ARPES measurement data (image, detail). (Courtesy: HZB)

Topics: Alternate Energy, Applied Physics, Battery, Chemistry, Civilization, Climate Change

A longstanding explanation for why perovskite materials make such good solar cells has been cast into doubt thanks to new measurements. Previously, physicists ascribed the favorable optoelectronic properties of lead halide perovskites to the behavior of quasiparticles called polarons within the material’s crystal lattice. Now, however, detailed experiments at Germany’s BESSY II synchrotron revealed that no large polarons are present. The work sheds fresh light on how perovskites can be optimized for real-world applications, including light-emitting diodes, semiconductor lasers, and radiation detectors as well as solar cells.

Lead halide perovskites belong to a family of crystalline materials with an ABX₃ structure, where A is cesium, methylammonium (MA), or formamidinium (FA); B is lead or tin; and X is chlorine, bromine, or iodine. They are promising candidates for thin-film solar cells and other optoelectronic devices because their tuneable bandgaps enable them to absorb light over a broad range of wavelengths in the solar spectrum. Charge carriers (electrons and holes) also diffuse through them over long distances. These excellent properties give perovskite solar cells a power conversion efficiency of more than 18%, placing them on a par with established solar-cell materials such as silicon, gallium arsenide, and cadmium telluride.

Researchers are still unsure, however, exactly why charge carriers travel so well in perovskites, especially since perovskites contain far more defects than established solar-cell materials. One hypothesis is that polarons – composite particles made up of an electron surrounded by a cloud of ionic phonons, or lattice vibrations – act as screens, preventing charge carriers from interacting with the defects.

Charge-transport mystery deepens in promising solar-cell materials, Isabelle Dumé, Physics World

Clean energy sources like wind turbines are part of Argonne’s decades-long effort to create a carbon-free economy. (Image by Shutterstock/Engel.ac.)

Topics: Battery, Biofuels, Climate Change, Existentialism, Global Warming

Reducing carbon dioxide emissions and removing them from the atmosphere is critical to the global fight against climate change. Called decarbonization, it is one of the focal points in the nation’s strategy to ensure a bright future for our planet and all who live on it.

The U.S. Department of Energy’s (DOE) Argonne National Laboratory has been at the forefront of the quest to decarbonize the U.S. economy for decades.

Argonne scientists are developing new materials for batteries and researching energy-efficient transportation and sustainable fuels. They are expanding carbon-free energy sources like nuclear and renewable power. Argonne researchers are also exploring ways to capture carbon dioxide from the air and from industrial sources, use it to produce chemicals, or store it in the ground.

The ultimate goal? To reduce the greenhouse gases that trap heat in the atmosphere and warm the planet.

An overview of Argonne’s lab-wide effort to create a carbon-free economy, Beth Burmahl, Argonne National Laboratory

Fast physics Formula E has created huge advances in electric vehicles off the racing circuit as well as on, but they still have drawbacks. (Courtesy: Luis Licona/EPA-EFE/Shutterstock)

Topics: Alternate Energy, Battery, Biofuels, Climate Change, Global Warming

Cars – and in particular racecars – might seem the villains in a world grappling with climate change. Racing Green: How Motorsport Science Can Change the World hopes to convince you of exactly the opposite, with science journalist Kit Chapman showing how motorsports not only pioneers new, planet-friendlier machines and materials, but saves lives on and off the track too.

The first part of Chapman’s argument tracks the historical development of cars and competition. His stories show how, from its start, racing has served as a research lab and proving ground for new technologies. The first organized motor races were competitions to encourage innovation, akin to today’s X-Prizes. In 1894 Le Petit Journal offered a purse for the first car to make it from Paris to Rouen, while later races emphasized pure speed or, like the legendary 24 Hours of Le Mans, endurance. Chapman provides a whirlwind tour through the development of the internal combustion engine-powered car and its damning limitations, including the copious greenhouse-gas emissions and the inability to ever achieve more than 50% thermal efficiency.

He then introduces us to new racing series like Formula E and Extreme E, which have changed electric cars “from an eccentric folly to the undisputed future of the automotive industry”. Chapman highlights the advantages of electric vehicles without glossing over their drawbacks: recycling challenges, the potential for difficult-to-extinguish fires resulting from thermal runaway, and ethical/sustainability issues surrounding the materials used. Throughout this section, he links motorsport advances with “real-life” applications. For example, the same flywheels that enabled Audi’s hybrid racecars to take all three podium spots at the 24 Hours of Le Mans in 2012 made London buses more energy efficient. Some connections are a little more tenuous than others, but they are uniformly fascinating.

Racing to save the planet, Diandra Leslie-Pelecky, author of The Physics of NASCAR and runs the blog buildingspeed.org, Physics World

GIF Source: Sci-Tech Daily

Topics: Alternate Energy, Battery, Green Tech, Nanotechnology, Quantum Mechanics

Note: I'm in the semifinals of the 3-Minute Thesis competition, so I decided to focus on my presentation. Wish me luck. This does, however, relate to our need as a species to get off fossil fuels as soon as possible, so things like Ukraine, Crimea, and the dismemberment of Jamal Khashoggi are not facilitated by our need for energy and our tolerance for tyrants.

Whether it’s photovoltaics or fusion, sooner or later, human civilization must turn to renewable energies. This is deemed inevitable considering the ever-growing energy demands of humanity and the finite nature of fossil fuels. As such, much research has been pursued in order to develop alternative sources of energy, most of which utilize electricity as the main energy carrier. The extensive R&D in renewables has been accompanied by gradual societal changes as the world adopted new products and devices running on renewables. The most striking change as of recently is the rapid adoption of electric vehicles. While they were hardly seen on the roads even 10 years ago, now millions of electric cars are being sold annually. The electric car market is one of the most rapidly growing sectors, and it helped propel Elon Musk to become the wealthiest man in the world.

Unlike traditional cars which derive energy from the combustion of hydrocarbon fuels, electric vehicles rely on batteries as the storage medium for their energy. For a long time, batteries had far lower energy density than those offered by hydrocarbons, which resulted in very low ranges of early electric vehicles. However, gradual improvement in battery technologies eventually allowed the drive ranges of electric cars to be within acceptable levels in comparison to gasoline-burning cars. It is no understatement that the improvement in battery storage technology was one of the main technical bottlenecks which had to be solved in order to kickstart the current electric vehicle revolution.

New Quantum Technology To Make Charging Electric Cars As Fast as Pumping Gas, Institute for Basic Science, Sci-Tech Daily

Reference: “Quantum Charging Advantage Cannot Be Extensive Without Global Operations” 21 March 2022, Physical Review Letters.

Image Source: Penn State College of Earth and Mineral Sciences, John A. Dutton, e-Education Institute

Topics: Alternate Energy, Battery, Biofuels, Climate Change, Environment, Politics

Want another reason to loathe Russia’s invasion of Ukraine? Just look at how it may completely doom the Paris climate accords — and our planet.

According to United Nations Secretary-General Antonio Guterres, the problem of climate change — which he admitted was “not solved” during the COP26 climate summit in Glasgow at the end of 2021 — “is getting worse” as Russia invades Ukraine.

As if things weren’t bad enough, Guterres insisted that the conflict is making climate change much worse, given how it’s disrupted fossil fuel supply chains in Europe.

“Countries could become so consumed by the immediate fossil fuel supply gap that they neglect or knee-cap policies to cut fossil fuel use,” Guterres said in a speech to The Economist‘s Sustainability Summit, his first climate change-focused addressed since COP26, continuing: “This is madness. Addiction to fossil fuels is mutually assured destruction.”

UN: Ukrainian War Fossil Fuel ‘Madness’ Might Destroy The Planet, Noor Al-Sibai, Futurism

"How do you ask a man to be the last man to die for a mistake?" John Kerry, C-SPAN, as spokesman for Veterans Against the Vietnam War, now the U.S. Special Presidential Envoy for Climate.

Paraphrased, "how rich are you as the last richest man on a dead planet?"

Topics: Battery, Energy, Green Tech, Research, Solid-State Physics

Janus, in Roman religion, the animistic spirit of doorways (januae) and archways (Jani). Janus and the nymph Camasene were the parents of Tiberinus, whose death in or by the river Albula caused it to be renamed Tiber. Source: Encylopedia Britannica

Over the past decade, lithium-ion batteries have seen stunning improvements in their size, weight, cost, and overall performance. (See Physics Today, December 2019, page 20.) But they haven’t yet reached their full potential. One of the biggest remaining hurdles has to do with the electrolyte, the material that conducts Li⁺ ions from anode to cathode inside the battery to drive the equal and opposite flow of charge in the external circuit.

Most commercial lithium-ion batteries use organic liquid electrolytes. The liquids are excellent conductors of Li⁺ ions, but they’re volatile and flammable, and they offer no defense against the whisker-like Li-metal dendrites that can build up between the electrodes and eventually short-circuit the battery. Because safety comes first, battery designers must sacrifice some performance in favor of not having their batteries catch fire.

A solid-state electrolyte could solve those problems. But what kind of solid conducts ions? An ordered crystal won’t do—when every site is filled in a crystalline lattice, Li⁺ ions have nowhere to move to. A solid electrolyte, therefore, needs to have a disordered, defect-riddled structure. It must also provide a polar environment to welcome the Li⁺ ions, but with no negative charges so strong that the Li⁺ ions stick to them and don’t let go.

For several years, Jenny Pringle, Maria Forsyth, and colleagues at Deakin University in Australia have been exploring a class of materials, called organic ionic plastic crystals (OIPCs), that could fit the bill. As a mix of positive and negative ions, an OIPC offers the necessary polar environment for conducting Li⁺. And because the constituent ions are organic, the researchers have lots of chemical leeways to design their shapes so they can’t easily fit together into a regular lattice but are forced to adopt a disordered, Li⁺-permeable structure.

Two-faced ions form a promising battery material, Johanna L. Miller, Physics Today

Video Source: New York Times

Topics: Battery, Chemistry, Climate Change, Environment, Politics

KASULO, Democratic Republic of Congo — A man in a pinstripe suit with a red pocket square walked around the edge of a giant pit one April afternoon where hundreds of workers often toil in flip-flops, burrowing deep into the ground with shovels and pickaxes.

His polished leather shoes crunched on dust the miners had spilled from nylon bags stuffed with cobalt-laden rocks.

The man, Albert Yuma Mulimbi, is a longtime power broker in the Democratic Republic of Congo and chairman of a government agency that works with international mining companies to tap the nation’s copper and cobalt reserves, used in the fight against global warming.

Mr. Yuma’s professed goal is to turn Congo into a reliable supplier of cobalt, a critical metal in electric vehicles, and shed its anything-goes reputation for tolerating an underworld where children are put to work and unskilled and ill-equipped diggers of all ages get injured or killed.

“We have to reorganize the country and take control of the mining sector,” said Mr. Yuma, who had pulled up to the Kasulo site in a fleet of SUVs carrying a high-level delegation to observe the challenges there.

But to many in Congo and the United States, Mr. Yuma himself is a problem. As chairman of Gécamines, Congo’s state-owned mining enterprise, he has been accused of helping to divert billions of dollars in revenues, according to confidential State Department legal filings reviewed by The New York Times and interviews with a dozen current and former officials in both countries.

Hunt for the ‘Blood Diamond of Batteries’ Impedes Green Energy Push, Dionne Searcey, and Eric Lipton, New York Times

Image Source: Visual Capitalist

Topics: Alternate Energy, Battery, Biofuels, Chemistry, Climate Change, Environment

California and the Biden administration are pushing incentives to make the United States a global leader in a market that’s beginning to boom: the production of lithium, the lightweight metal needed for the batteries of electric vehicles, and for the storage of renewable energy from power plants.

At the moment nearly all the lithium used in the United States must be imported from China and other nations. But that trend could shift within two years if an efficient method is found to remove lithium from power plant waste in California.

Since the 1970s, California has built power plants that make electricity from geothermal energy—steam from saltwater heated by magma from the molten core of the Earth. It now accounts for 6 percent of California’s power, but it is more expensive to produce than other forms of renewable energy, such as solar and wind power.

But that calculus could change if the wastewater from the process—a whitish, soup-like brine that contains a mixture of dissolved minerals and metals including lithium—can be separated so the lithium could be extracted.

According to a study by the Department of Energy, the Salton Sea in California’s Imperial Valley—one of two large geothermal energy production sites in the state—could produce as much as 600,000 tons of lithium annually.

U.S. Looks to Extract Lithium for Batteries from Geothermal Waste, John Fialka, Scientific American

An aerial view of peat fields in Elva, Estonia. September 30, 2021. REUTERS/Janis Laizans

Topics: Battery, Biofuels, Chemistry, Energy, Green Tech

TARTU, Estonia, Oct 11 (Reuters) - Peat, plentiful in bogs in northern Europe, could be used to make sodium-ion batteries cheaply for use in electric vehicles, scientists at an Estonian university say.

Sodium-ion batteries, which do not contain relatively costly lithium, cobalt, or nickel, are one of the new technologies that battery makers are looking at as they seek alternatives to the dominant lithium-ion model.

Scientists at Estonia's Tartu University say they have found a way to use peat in sodium-ion batteries, which reduces the overall cost, although the technology is still in its infancy.

"Peat is a very cheap raw material - it doesn't cost anything, really," says Enn Lust, head of the Institute of Chemistry at the university.

Energy from bogs: Estonian scientists use peat to make batteries, Janis Laizans and Andrius Sytas, Reuters Science

The black phosphorus composite material connected by carbon-phosphorus covalent bonds has a more stable structure and a higher lithium-ion storage capacity. Credit: DONG Yihan, SHI Qianhui, and LIANG Yan

Topics: Alternative Energy, Applied Physics, Battery, Nanotechnology, Research

A new electrode material could make it possible to construct lithium-ion batteries with a high charging rate and storage capacity. If scaled up, the anode material developed by researchers at the University of Science and Technology of China (USTC) and colleagues in the US might be used to manufacture batteries with an energy density of more than 350 watt-hours per kilogram – enough for a typical electric vehicle (EV) to travel 600 miles on a single charge.

Lithium ions are the workhorse in many common battery applications, including electric vehicles. During operation, these ions move back and forth between the anode and cathode through an electrolyte as part of the battery’s charge-discharge cycle. A battery’s performance thus depends largely on the materials used in the electrodes and electrolyte, which need to be able to store and transfer many lithium ions in a short period – all while remaining electrochemically stable – so they can be recharged hundreds of times. Maximizing the performance of all these materials at the same time is a longstanding goal of battery research, yet in practice, improvements in one usually come at the expense of the others.

“A typical trade-off lies in the storage capacity and rate capability of the electrode material,” co-team leader Hengxing Ji tells Physics World. “For example, anode materials with high lithium storage capacity, such as silicon, are usually reported as having low lithium-ion conductivity, which hinders fast battery [charging]. As a result, the increase in battery capacity usually leads to a long charging time, which represents a critical roadblock for more widespread adoption of EVs.”

Black phosphorus composite makes a better battery, Isabelle Dumé, Physics World