nanomaterials (5)

Stronger Than Steel...

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Researchers from the University of Connecticut and colleagues have created a highly durable, lightweight material by structuring DNA and then coating it in glass. The resulting product, characterized by its nanolattice structure, exhibits a unique combination of strength and low density, making it potentially useful in applications like vehicle manufacturing and body armor. (Artist’s concept.)

Topics: Biotechnology, DNA, Material Science, Nanomaterials

Researchers have developed a highly robust material with an extremely low density by constructing a structure using DNA and subsequently coating it in glass.

Materials possessing both strength and lightness have the potential to enhance everything from automobiles to body armor. But usually, the two qualities are mutually exclusive. However, researchers at the University of Connecticut, along with their collaborators, have now crafted an incredibly strong yet lightweight material. Surprisingly, they achieved this using two unexpected building blocks: DNA and glass.

“For the given density, our material is the strongest known,” says Seok-Woo Lee, a materials scientist at UConn. Lee and colleagues from UConn, Columbia University, and Brookhaven National Lab reported the details on July 19 in Cell Reports Physical Science.

Strength is relative. Iron, for example, can take 7 tons of pressure per square centimeter. But it’s also very dense and heavy, weighing 7.8 grams/cubic centimeter. Other metals, such as titanium, are stronger and lighter than iron. And certain alloys combining multiple elements are even stronger. Strong, lightweight materials have allowed for lightweight body armor and better medical devices and made safer, faster cars and airplanes.

Scientists Create New Material Five Times Lighter and Four Times Stronger Than Steel. Sci-Tech Daily

Reference: “High-strength, lightweight nano-architected silica” by Aaron Michelson, Tyler J. Flanagan, Seok-Woo Lee, and Oleg Gang, 27 June 2023, Cell Reports Physical Science.
DOI: 10.1016/j.xcrp.2023.101475

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Build Better Batteries...

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Electric field- and pressure-assisted fast sintering to control graphene alignment in thick composite electrodes for boosting lithium storage performance. Credit: Hongtao Sun, Penn State

Topics: Battery, Energy, Graphene, Green Tech, Lithium, Materials Science, Nanomaterials

The demand for high-performance batteries, especially for use in electric vehicles, is surging as the world shifts its energy consumption to a more electric-powered system, reducing reliance on fossil fuels and prioritizing climate remediation efforts. To improve battery performance and production, Penn State researchers and collaborators have developed a new fabrication approach that could make for more efficient batteries that maintain energy and power levels.

The improved method for fabricating battery electrodes may lead to high-performance batteries that would enable more energy-efficient electric vehicles, as well as such benefits as enhancing power grid storage, according to Hongtao Sun. Sun is an assistant professor of industrial and manufacturing engineering at Penn State and the co-corresponding author of the study, which was published in and featured on the front cover of Carbon.

"With current batteries, we want them to enable us to drive a car for longer distances, and we want to charge the car in maybe five minutes, 10 minutes, comparable to the time it takes to fill up for gas," Sun said. "In our work, we considered how we can achieve this by making the electrodes and battery cells more compact, with a higher percentage of active components and a lower percentage of passive components."

If an electric car maker wants to improve the driving distance of their vehicles, they add more battery cells, numbering in the thousands. The smaller and lighter, the better, according to Sun.

"The solution for longer driving distances for an electric vehicle is just to add compact batteries, but with denser and thicker electrodes," Sun said, explaining that such electrodes could better connect and power the battery's components, making them more active. "Although this approach may slightly reduce battery performance per electrode weight, it significantly enhances the vehicle's overall performance by reducing the battery package's weight and the energy required to move the electric vehicle."

Thicker, denser, better: New electrodes may hold the key to advanced batteries, Jamie Oberdick, Pennsylvania State University, techxplore.

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Beyond Attogram Imaging...

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When X-rays (blue color) illuminate an iron atom (red ball at the center of the molecule), core-level electrons are excited. X-ray excited electrons are then tunneled to the detector tip (gray) via overlapping atomic/molecular orbitals, which provide elemental and chemical information about the iron atom. Credit: Saw-Wai Hla

Topics: Applied Physics, Instrumentation, Materials Science, Nanomaterials, Quantum Mechanics

A team of scientists from Ohio University, Argonne National Laboratory, the University of Illinois-Chicago, and others, led by Ohio University Professor of Physics, and Argonne National Laboratory scientist, Saw Wai Hla, have taken the world's first X-ray SIGNAL (or SIGNATURE) of just one atom. This groundbreaking achievement could revolutionize the way scientists detect materials.

Since its discovery by Roentgen in 1895, X-rays have been used everywhere, from medical examinations to security screenings in airports. Even Curiosity, NASA's Mars rover, is equipped with an X-ray device to examine the material composition of the rocks on Mars. An important usage of X-rays in science is to identify the type of materials in a sample. Over the years, the quantity of materials in a sample required for X-ray detection has been greatly reduced thanks to the development of synchrotron X-rays sources and new instruments. To date, the smallest amount one can X-ray a sample is in an attogram, which is about 10,000 atoms or more. This is due to the X-ray signal produced by an atom being extremely weak, so conventional X-ray detectors cannot be used to detect it. According to Hla, it is a long-standing dream of scientists to X-ray just one atom, which is now being realized by the research team led by him.

"Atoms can be routinely imaged with scanning probe microscopes, but without X-rays, one cannot tell what they are made of. We can now detect exactly the type of a particular atom, one atom-at-a-time, and can simultaneously measure its chemical state," explained Hla, who is also the director of the Nanoscale and Quantum Phenomena Institute at Ohio University. "Once we are able to do that, we can trace the materials down to the ultimate limit of just one atom. This will have a great impact on environmental and medical sciences and maybe even find a cure that can have a huge impact on humankind. This discovery will transform the world."

Their paper, published in the scientific journal Nature on May 31, 2023, and gracing the cover of the print version of the scientific journal on June 1, 2023, details how Hla and several other physicists and chemists, including Ph.D. students at OHIO, used a purpose-built synchrotron X-ray instrument at the XTIP beamline of Advanced Photon Source and the Center for Nanoscale Materials at Argonne National Laboratory.

Scientists report the world's first X-ray of a single atom, Ohio University, Phys.org.

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Mice, Men, and Nanoparticles...

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Graphical abstract. Credit: Nanomaterials (2023). DOI: 10.3390/nano13081404

Topics: Biology, Environment, Nanomaterials, Nanotechnology

Among the biggest environmental problems of our time, micro- and nanoplastic particles (MNPs) can enter the body in various ways, including through food. And now, for the first time, research conducted at MedUni Vienna has shown how these minute particles manage to breach the blood-brain barrier and, consequently, penetrate the brain. The newly discovered mechanism provides the basis for further research to protect humans and the environment.

Published in the journal Nanomaterials, the study was carried out in an animal model with oral administration of MNPs, in this case, polystyrene, a widely-used plastic found in food packaging. Led by Lukas Kenner (Department of Pathology at MedUni Vienna and Department of Laboratory Animal Pathology at Vetmeduni) and Oldamur Hollóczki (Department of Physical Chemistry, University of Debrecen, Hungary), the research team was able to determine that tiny polystyrene particles could be detected in the brain just two hours after ingestion.

The mechanism that enabled them to breach the blood-brain barrier was previously unknown to medical science. "With the help of computer models, we discovered that a certain surface structure (biomolecular corona) was crucial in enabling plastic particles to pass into the brain," Oldamur Hollóczki explained.

Study shows how tiny plastic particles manage to breach the blood-brain barrier, Medical University of Vienna, Phys.org

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Magnetic Plasmons in Nanostructures...

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FIG. 1. (a) Sketches of the excitations of surface plasmons polaritons - SPP (top), localized surface plasmons - LSP (middle), and magnetic plasmons - MP (bottom). All these excitations are associated with a collective motion of surface charges under light illumination. (b) Diagram of MP-based plasmonic nanostructures used for fundamental studies and their applications in various research fields.

Topics: Electromagnetism, Magnetism, Metamaterials, Nanoclusters, Nanomaterials, Plasmonic Nanostructures

Abstract

The magnetic response of most natural materials, characterized by magnetic permeability, is generally weak. Particularly in the optical range, the weakness of magnetic effects is directly related to the asymmetry between electric and magnetic charges. Harnessing artificial magnetism started with a pursuit of metamaterial design exhibiting magnetic properties. A plasmonic nanostructure called split-ring resonators gave the first demonstration of artificial magnetism. Engineered circulating currents form magnetic plasmons, acting as the source of artificial magnetism in response to external electromagnetic excitation. In the past two decades, magnetic plasmons supported by plasmonic nanostructures have become an active topic of study. This Perspective reviews the latest studies on magnetic plasmons in plasmonic nanostructures. A comprehensive summary of various plasmonic nanostructures supporting magnetic plasmons, including split-ring resonators, metal–insulator–metal structures, metallic deep groove arrays, and plasmonic nanoclusters, is presented. Fundamental studies and applications based on magnetic plasmons are discussed. The formidable challenges and the prospects of the future study directions on developing magnetic plasmonic nanostructures are proposed.

Magnetic plasmons in plasmonic nanostructures: An overview

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