solid-state physics (3)

OIPCs and Janus...


Topics: Battery, Energy, Green Tech, Research, Solid-State Physics

Janus, in Roman religion, the animistic spirit of doorways (januae) and archways (Jani). Janus and the nymph Camasene were the parents of Tiberinus, whose death in or by the river Albula caused it to be renamed Tiber. Source: Encylopedia Britannica

Over the past decade, lithium-ion batteries have seen stunning improvements in their size, weight, cost, and overall performance. (See Physics Today, December 2019, page 20.) But they haven’t yet reached their full potential. One of the biggest remaining hurdles has to do with the electrolyte, the material that conducts Li+ ions from anode to cathode inside the battery to drive the equal and opposite flow of charge in the external circuit.

Most commercial lithium-ion batteries use organic liquid electrolytes. The liquids are excellent conductors of Li+ ions, but they’re volatile and flammable, and they offer no defense against the whisker-like Li-metal dendrites that can build up between the electrodes and eventually short-circuit the battery. Because safety comes first, battery designers must sacrifice some performance in favor of not having their batteries catch fire.

A solid-state electrolyte could solve those problems. But what kind of solid conducts ions? An ordered crystal won’t do—when every site is filled in a crystalline lattice, Li+ ions have nowhere to move to. A solid electrolyte, therefore, needs to have a disordered, defect-riddled structure. It must also provide a polar environment to welcome the Li+ ions, but with no negative charges so strong that the Li+ ions stick to them and don’t let go.

For several years, Jenny PringleMaria Forsyth, and colleagues at Deakin University in Australia have been exploring a class of materials, called organic ionic plastic crystals (OIPCs), that could fit the bill. As a mix of positive and negative ions, an OIPC offers the necessary polar environment for conducting Li+. And because the constituent ions are organic, the researchers have lots of chemical leeways to design their shapes so they can’t easily fit together into a regular lattice but are forced to adopt a disordered, Li+-permeable structure.

Two-faced ions form a promising battery material, Johanna L. Miller, Physics Today

Read more…

Pairs of Cooper Pairs...


New state of matter: The team observed electron quadruplets in this iron-based superconductor material, seen mounted for experimental measurements. (Courtesy: Vadim Grinenko, Federico Caglieris)

Topics: Condensed Matter Physics, Solid-State Physics, Superconductors

Note: I gave my research proposal last Friday. I have been answering some concerns about my proposal for the committee. I followed the outline sent to me by my advisor. I hope I've answered them sufficiently. I will post today and tomorrow; next week on Monday, Wednesday, and Friday. I tutor Calculus. For a person finished with classes, I'm extremely busy.

Cool a material below its superconducting transition temperature and you’d expect it to start conducting electricity without resistance and expelling magnetic fields. But an international group of physicists has found that a certain kind of iron-based material doped with negative charges does the opposite at around the same temperature – producing spontaneous magnetic fields and retaining resistance when chilled. The researchers say that the results point to a new state of matter in which electrons flow in correlated groups of four, rather than two.

According to the Bardeen-Cooper-Schrieffer (BCS) theory, superconductivity occurs when electrons get together to form what is known as Cooper pairs. Whereas in a vacuum two electrons would repel each other, when moving through the crystal lattice of a superconducting material, one of these particles shifts the positions of surrounding atoms to leave a small region of positive charge. This attracts the second electron to create the pair.

The creation of many such pairs yields a collective condensate, which results in frictionless electron flow. This occurs below a certain temperature – the superconducting transition temperature (Tc) – at which point atoms lack the thermal energy to break up the pairs.

Superconductor reveals new state of matter involving pairs of Cooper pairs, Edwin Cartlidge, Physics World

Read more…

Gold Anniversary...


Images are from the article, link below

Topics: Electrical Engineering, Materials Science, Nanotechnology, Solid-State Physics

It's not exactly a wedding anniversary, but it is significant.

Fifty years ago this month, Intel introduced the first commercial microprocessor, the 4004. Microprocessors are tiny, general-purpose chips that use integrated circuits made up of transistors to process data; they are the core of a modern computer. Intel created the 12 mm2 chip for a printing calculator made by the Japanese company Busicom. The 4004 had 2,300 transistors—a number dwarfed by the billions found in today’s chips. But the 4004 was leaps and bounds ahead of its predecessors, packing the computing power of the room-sized, vacuum tube-based first computers into a chip the size of a fingernail. In the past 50 years, microprocessors have changed our culture and economy in unimaginable ways.

The microprocessor turns 50, Katherine Bourzac, Chemical & Engineering News

Read more…