BLOGS

Topics: Chemistry, Computer Science, Quantum Computer, Quantum Mechanics

Scientists at the University of Sydney have, for the first time, used a quantum computer to engineer and directly observe a process critical in chemical reactions by slowing it down by a factor of 100 billion times.

Joint lead researcher and Ph.D. student Vanessa Olaya Agudelo said, "It is by understanding these basic processes inside and between molecules that we can open up a new world of possibilities in materials science, drug design, or solar energy harvesting.

"It could also help improve other processes that rely on molecules interacting with light, such as how smog is created or how the ozone layer is damaged."

Specifically, the research team witnessed the interference pattern of a single atom caused by a common geometric structure in chemistry called a "conical intersection."

Conical intersections are known throughout chemistry and are vital to rapid photochemical processes such as light harvesting in human vision or photosynthesis.

Chemists have tried to directly observe such geometric processes in chemical dynamics since the 1950s, but it is not feasible to observe them directly, given the extremely rapid timescales involved.

To get around this problem, quantum researchers in the School of Physics and the School of Chemistry created an experiment using a trapped-ion quantum computer in a completely new way. This allowed them to design and map this very complicated problem onto a relatively small quantum device—and then slow the process down by a factor of 100 billion. Their research findings are published August 28 in Nature Chemistry.

"In nature, the whole process is over within femtoseconds," said Olaya Agudelo from the School of Chemistry. "That's a billionth of a millionth—or one quadrillionth—of a second.

"Using our quantum computer, we built a system that allowed us to slow down the chemical dynamics from femtoseconds to milliseconds. This allowed us to make meaningful observations and measurements.

"This has never been done before."

Joint lead author Dr. Christophe Valahu from the School of Physics said, "Until now, we have been unable to directly observe the dynamics of 'geometric phase'; it happens too fast to probe experimentally.

"Using quantum technologies, we have addressed this problem."

Scientists use a quantum device to slow down simulated chemical reactions 100 billion times. University of Sydney, Phys.org.

The central role of HFIP: a solvent component that solvates POM. a. 1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP): an effective solvent for polyoxymethylene (POM), the clustering of HFIP enabled the decrease of σ*OH energy38. b. Images of an undivided cell before (left) and after (right) the electrolysis. c. Reaction profile of POM bulk electrolysis at 3.5 V (60 °C), 0.1 M LiClO4 in CH3CN: HFIP (26:4). Credit: Nature Communications (2023). DOI: 10.1038/s41467-023-39362-z

Topics: Chemistry, Green Tech, Materials Science, Star Trek

A group of researchers at the University of Illinois Urbana-Champaign demonstrated a way to use the renewable energy source of electricity to recycle a form of plastic that's growing in use but more challenging to recycle than other popular forms of plastic.

In their study recently published in Nature Communications, they share their innovative process that shows the potential for harnessing renewable energy sources in the shift toward a circular plastics economy.

"We wanted to demonstrate this concept of bringing together renewable energy and a circular plastic economy," said Yuting Zhou, a postdoctoral associate, and co-author, who worked on this groundbreaking research with two professors in chemistry at Illinois, polymer expert Jeffrey Moore and electrochemistry expert Joaquín Rodríguez-López.

The project was conceived by Moore, who had experience working with Poly(phthalaldehyde), a form of polyacetal. Polyoxymethylene (POM) is a high-performance acetal resin that is used in a variety of industries, including automobiles and electronics. A thermoplastic, it can be shaped and molded when heated and hardens upon cooling with a high degree of strength and rigidity, making it an attractive lighter alternative to metal in some applications, like mechanical gears in automobiles. It is produced by various chemical firms with slightly different formulas and names, including Delrin by DuPont.

When recycling, those highly crystalline properties of POM make it difficult to break down. It can be melted and molded again, but POM's original material properties are lost, limiting the usefulness of the recycled material.

"When the polymer was in use as a product, it was not a pure polymer. It will also have other chemicals like coloring additives and antioxidants. So, if you simply melt it and remold it, the material properties are always lost," Zhou explained.

The Illinois research team's method uses electricity, which can be drawn from renewable sources, and takes place at room temperature.

This electro-mediated process deconstructs the polymer, breaking it down into monomers—the molecules that are bonded to other identical molecules to form polymers.

A recycling study demonstrates new possibilities for a circular plastics economy powered by renewable energy, Tracy Crane, University of Illinois at Urbana-Champaign.

Mick Fleetwood's Maui Restaurant destroyed in Maui fire. Allison Rapp, Ultimate Classic Rock

Topics: Battery, Chemistry, Civics, Civilization, Climate Change, Democracy, Existentialism

The Herculoids were a Hanna-Barbara cartoon that only ran for two seasons, from 1967 to 1969. From ages five to seven, I didn't demand much from my Saturday morning viewing pleasure: good guys, bad guys, action, good guys pummel bad guys, in this case, casting them off the planet. We landed on the Moon in their last year of air (it's a shame that history is now controversial). Dr. King and Robert Kennedy were assassinated In Medias Res. My understanding of Physics and STEM came much later.

Zandor, Tara, and Domo were the human protagonists defending planet "Amzot" (the writers threw spaghetti at the wall on this name). In a tepid reboot, they called it Quasar, a little more astrophysical but nonetheless kooky. They had a laser ray dragon (Zot), a rock ape (Igo), and a ten-legged rhino/triceratops hybrid that shot energy rocks from his snout (Tondro, the Terrific, because, yeah). Gloop and Gleep were human-sized, protoplasmic creatures called "the formless, fearless wonders," with eyes, and Gleep, was somehow the "son" of Gloop, without genitalia or gender (go with the bit?). The humans also shot energy rocks from slingshots at the foes too dumb to leave Zandor and his jungle planet alone. If the rocks were made of Lithium, they shouldn't have lasted too long: one of its properties is its volatility in oxygenated atmospheres.

In 1967, I would have been five years old and not too demanding of my visual entertainment on Saturday Morning Cartoons, as this old form pastime was called.

Taking a few courses in Physics drives a probing question and observation:

Where were the flocks of laser ray dragons, the congress of rock apes, the herds of rhino/triceratops hybrids, and what marshy bog did the "formless, fearless wonders" ascend from? It seemed Zot, Igo, Tondro, Gloop, and Gleep were the only ones of their kind.

In "Sarko: The Arkman," Sarko kidnaps Domo, Igo, and Tondro for his "collection" on another planet. Zandor rides Zot with Gloop to ANOTHER PLANET without the need of a spaceship, escape velocity, pressurized spacesuits, protection from radiation, or the friction of reentry to Sarko's world. Even if the planet was in the same orbital plane as Amzot, it didn't appear to take him long, and he wasn't bruised by a single meteor during the trip nor tanned from radiation burns (or dead). Gleep clones five copies of himself to protect Tara then turns up in a scene making himself a pillow on Sarko's world to catch Domo. Zot flew escort to Sarko's ship on the way back to Amzot again, with no loss of life. Did you follow all that?

Five-year-olds don't need Physics lessons, just a simple plot, a lot of action, and taking care of "evil-doers" before you play outside after Saturday cartoons.

It's magical thinking, but not a way to run human society.

"The human understanding is no dry light but receives an infusion from the will and affections; whence proceed sciences which may be called 'sciences as one would.' For what a man had rather were true, he more readily believes. Therefore, he rejects difficult things from impatience of research; sober things because they narrow hope; the deeper things of nature, from superstition; the light of experience, from arrogance and pride; things not commonly believed, out of the deference to the opinion of the vulgar. Numberless, in short, are the ways, and sometimes imperceptible, in which the affections color and infect the understanding."

Sir Francis Bacon, NOVUM ORGANON (1620)

Maui is a dystopian hellscape. It is now the deadliest wildfire in American history: until the next one. Reuters reports the cause of the fire is unknown, but 85% of all wildfires are caused by humans, as is the anthropogenic climate disruption that helped light the match. Hurricane Dora energized the spread, fanning the flames across the island that was experiencing a drought. Part of Maui's problem is prior to the predictions of climate scientists coming true in recent real-time, Maui never had to prepare for drought conditions or massive wildfires. Did I mention the island chain is surrounded by the Pacific Ocean?

Maui was the Capitol of the old kingdom of Hawaii before colonization. It was a tourist attraction and the seat of culture. Maui is the place where the Hula dance and the Samoan language were reconstituted and practiced. A 150-year-old banyan tree burned in the flames. It will survive IF the roots survived the savage flames.

"Some 271 structures were destroyed or damaged, the Honolulu Star-Advertiser said, citing official reports from the U.S. Civil Air Patrol and Maui Fire Department." Reuters

There is a throughline from Hurricane Katrina in Louisiana and Hurricane Dora in Maui. That throughline is climate change, gestated into the climate crisis, birthed into climate catastrophe. In eighteen years, we have shuffled, obfuscated, and kicked the can down the road right into our children's and grandchildren's future. We have allowed political operators and lobbyists for the fossil fuels industry to quote their "science as one would": "It's summer." "There is no climate change." "It's a (fill in the blank) hoax." "How can there be global warming if New York is blanketed in snow?"

The tobacco and fossil fuels industry used the same researchers and same lawyers to sway public opinion and sell their products. It is a myopic concentration on quarterly profits, not looking at the damage to the planet beneath them going forward. If Adam Smith's capitalism is our "salvation," there should be market-based solutions to ensure a functional civilization as corporations pursue profits and bought and paid-for politicians pursue policies that sustain both commerce and civilization.

Otherwise, their vulgar opinions have not offered solutions nor modeled societal collapse.

The Guardian reported from the National Academy of Science that more than 50% of life is in the soil beneath us. Life on Earth may survive our own hubris. It likely won't be intelligent or anything resembling human civilization.

Cartoon Network Physics is only good for five-year-olds on Saturday morning cartoons. There are no laser dragons, rock apes, rhino/triceratops-hybrids, and energy rocks to deploy to our rescue. It fails humanity in the long term. "Sciences as one would" has led us to this precipice. "Sciences as one acknowledges" will lead us away from it.

Note: The blog will resume Monday - Friday postings on August 21st (traveling for work).

Chip off the old block: Intel’s Tunnel Falls chip is based on silicon spin qubits, which are about a million times smaller than other qubit types. (Courtesy: Intel Corporation)

Topics: Applied Physics, Chemistry, Electrical Engineering, Quantum Computer, Quantum Mechanics

Intel – the world’s biggest computer-chip maker – has released its newest quantum chip and has begun shipping it to quantum scientists and engineers to use in their research. Dubbed Tunnel Falls, the chip contains a 12-qubit array and is based on silicon spin-qubit technology.

The distribution of the quantum chip to the quantum community is part of Intel’s plan to let researchers gain hands-on experience with the technology while at the same time enabling new quantum research.

The first quantum labs to get access to the chip include the University of Maryland, Sandia National Laboratories, the University of Rochester, and the University of Wisconsin-Madison.

The Tunnel Falls chip was fabricated on 300 mm silicon wafers in Intel’s “D1” transistor fabrication facility in Oregon, which can carry out extreme ultraviolet lithography (EUV) and gate and contact processing techniques.

Intel releases 12-qubit silicon quantum chip to the quantum community, Martijn Boerkamp, Physics World.

Topics: Applied Physics, Chemistry, Computer Science, Electrical Engineering, Materials Science, Nanotechnology, Quantum Mechanics, Semiconductor Technology

Gordon Moore, the co-founder of Intel who died earlier this year, is famous for forecasting a continuous rise in the density of transistors that we can pack onto semiconductor chips. James McKenzie looks at how “Moore’s law” is still going strong after almost six decades but warns that further progress is becoming harder and ever more expensive to sustain.

When the Taiwan Semiconductor Manufacturing Company (TSMC) announced last year that it was planning to build a new factory to produce integrated circuits, it wasn’t just the eye-watering $33bn price tag that caught my eye. What also struck me is that the plant, set to open in 2025 in the city of Hsinchu, will make the world’s first “2-nanometer” chips. Smaller, faster, and up to 30% more efficient than any microchip that has come before, TSMC’s chips will be sold to the likes of Apple – the company’s biggest customer – powering everything from smartphones to laptops.

But our ability to build such tiny, powerful chips shouldn’t surprise us. After all, the engineer Gordon Moore – who died on 24 March this year, aged 94 – famously predicted in 1965 that the number of transistors we can squeeze onto an integrated circuit ought to double yearly. Writing for the magazine Electronics (38 114), Moore reckoned that by 1975 it should be possible to fit a quarter of a million components onto a single silicon chip with an area of one square inch (6.25 cm²).

Moore’s prediction, which he later said was simply a “wild extrapolation”, held true, although, in 1975, he revised his forecast, predicting that chip densities would double every two years rather than every year. What thereafter became known as “Moore’s law” proved amazingly accurate, as the ability to pack ever more transistors into a tiny space underpinned the almost non-stop growth of the consumer electronics industry. In truth, it was never an established scientific “law” but more a description of how things had developed in the past as well as a roadmap that the semiconductor industry imposed on itself, driving future development.

Moore's law: further progress will push hard on the boundaries of physics and economics, James McKenzie, Physics World

An RNA-making molecule crystallizes on magnetite, which can bias the process toward a single chiral form. S. FURKAN OZTURK

Topics: Biology, Biotechnology, Chemistry, Magnetism, Materials Science

In 1848, French chemist Louis Pasteur discovered that some molecules essential for life exist in mirror-image forms, much like our left and right hands. Today, we know biology chooses just one of these “chiral” forms: DNA, RNA, and their building blocks are all right-handed, whereas amino acids and proteins are all left-handed. Pasteur, who saw hints of this selectivity, or “homochirality,” thought magnetic fields might somehow explain it, but its origin has remained one of biology’s great mysteries. Now, it turns out Pasteur may have been onto something.

In three new papers, researchers suggest magnetic minerals common on early Earth could have caused key biomolecules to accumulate on their surface in just one mirror image form, setting off positive feedback that continued to favor the same form. “It’s a real breakthrough,” says Jack Szostak, an origin of life chemist at the University of Chicago who was not involved with the new work. “Homochirality is essential to get biology started, and this is [a possible]—and I would say very likely—solution.”

Chemical reactions are typically unbiased, yielding equal amounts of right- and left-handed molecules. But life requires selectivity: Only right-handed DNA, for example, has the correct twist to interact properly with other chiral molecules. To get [life], “you’ve got to break the mirror, or you can’t pull it off,” says Gerald Joyce, an origin of life chemist and president of the Salk Institute for Biological Studies.

Over the past century, researchers have proposed various mechanisms for skewing the first biomolecules, including cosmic rays and polarized light. Both can cause an initial bias favoring either right- or left-handed molecules, but they don’t directly explain how this initial bias was amplified to create the large reservoirs of chiral molecules likely needed to make the first cells. An explanation that creates an initial bias is a good start but “not sufficient,” says Dimitar Sasselov, a physicist at Harvard University and a leader of the new work.

‘Breakthrough’ could explain why life molecules are left- or right-handed, Robert F. Service, Science.org.

An X-ray flash illuminates a molecule. Credit: Raphael Jay

Topics: Chemistry, Climate Change, Green Tech, High Energy Physics, Research, X-rays

The use of short flashes of X-ray light brings scientists one big step closer to developing better catalysts to transform the greenhouse gas methane into a less harmful chemical. The result, published in the journal Science, reveals for the first time how carbon-hydrogen bonds of alkanes break and how the catalyst works in this reaction.

Methane, one of the most potent greenhouse gases, is being released into the atmosphere at an increasing rate by livestock farming and the unfreezing of permafrost. Transforming methane and longer-chain alkanes into less harmful and, in fact, useful chemicals would remove the associated threats and, in turn, make a huge feedstock for the chemical industry available. However, transforming methane necessitates, as a first step, the breaking of a C-H bond, one of the strongest chemical linkages in nature.

Forty years ago, molecular metal catalysts that can easily split C-H bonds were discovered. The only thing found to be necessary was a short flash of visible light to "switch on" the catalyst, and, as by magic, the strong C-H bonds of alkanes passing nearby are easily broken almost without using any energy. Despite the importance of this so-called C-H activation reaction, it remained unknown over the decades how that catalyst performs this function.

The research was led by scientists from Uppsala University in collaboration with the Paul Scherrer Institute in Switzerland, Stockholm University, Hamburg University, and the European XFEL in Germany. For the first time, the scientists were able to directly watch the catalyst at work and reveal how it breaks those C-H bonds.

In two experiments conducted at the Paul Scherrer Institute in Switzerland, the researchers were able to follow the delicate exchange of electrons between a rhodium catalyst and an octane C-H group as it gets broken. Using two of the most powerful sources of X-ray flashes in the world, the X-ray laser SwissFEL and the X-ray synchrotron Swiss Light Source, the reaction could be followed all the way from the beginning to the end. The measurements revealed the initial light-induced activation of the catalyst within 400 femtoseconds (0.0000000000004 seconds) to the final C-H bond breaking after 14 nanoseconds (0.000000014 seconds).

X-rays visualize how one of nature's strongest bonds breaks, Uppsala University, Phys.org.

Prof. Li Gang invented a novel technique to achieve breakthrough efficiency with organic solar cells. Credit: Hong Kong Polytechnic University

Topics: Chemistry, Green Tech, Materials Science, Photonics, Research, Solar Power

Researchers from The Hong Kong Polytechnic University (PolyU) have achieved a breakthrough power-conversion efficiency (PCE) of 19.31% with organic solar cells (OSCs), also known as polymer solar cells. This remarkable binary OSC efficiency will help enhance these advanced solar energy device applications.

The PCE, a measure of the power generated from a given solar irradiation, is considered a significant benchmark for the performance of photovoltaics (PVs), or solar panels, in power generation. The improved efficiency of more than 19% that was achieved by the PolyU researchers constitutes a record for binary OSCs, which have one donor and one acceptor in the photoactive layer.

Led by Prof. Li Gang, Chair Professor of Energy Conversion Technology, and Sir Sze-Yen Chung, Endowed Professor in Renewable Energy at PolyU, the research team invented a novel OSC morphology-regulating technique by using 1,3,5-trichlorobenzene as a crystallization regulator. This new technique boosts OSC efficiency and stability.

The team developed a non-monotonic intermediated state manipulation (ISM) strategy to manipulate the bulk-heterojunction (BHJ) OSC morphology and simultaneously optimize the crystallization dynamics and energy loss of non-fullerene OSCs. Unlike the strategy of using traditional solvent additives, which is based on excessive molecular aggregation in films, the ISM strategy promotes the formation of more ordered molecular stacking and favorable molecular aggregation. As a result, the PCE was considerably increased, and the undesirable non-radiative recombination loss was reduced. Notably, non-radiative recombination lowers the light generation efficiency and increases heat loss.

Researchers achieve a record 19.31% efficiency with organic solar cells. Hong Kong Polytechnic University. Tech Explore

The disinfectant powder is stirred in bacteria-contaminated water (upper left). The mixture is exposed to sunlight, which rapidly kills all the bacteria (upper right). A magnet collects the metallic powder after disinfection (lower right). The powder is then reloaded into another beaker of contaminated water, and the disinfection process is repeated (lower left). (Image credit: Tong Wu/Stanford University)

Topics: Biology, Chemistry, Environment, Materials Science, Nanotechnology

When exposed to sunlight, a low-cost, recyclable powder can kill thousands of waterborne bacteria per second. Stanford and SLAC scientists say the ultrafast disinfectant could be a revolutionary advance for 2 billion people worldwide without access to safe drinking water.

At least 2 billion people worldwide routinely drink water contaminated with disease-causing microbes.

Now, scientists at Stanford University and SLAC National Accelerator Laboratory have invented a low-cost, recyclable powder that kills thousands of waterborne bacteria per second when exposed to ordinary sunlight. According to the Stanford and SLAC team, the discovery of this ultrafast disinfectant could be a significant advance for nearly 30 percent of the world’s population with no access to safe drinking water. Their results are published in a May 18 study in Nature Water.

“Waterborne diseases are responsible for 2 million deaths annually, the majority in children under the age of 5,” said study co-lead author Tong Wu, a former postdoctoral scholar of materials science and engineering (MSE) at the Stanford School of Engineering. “We believe that our novel technology will facilitate revolutionary changes in water disinfection and inspire more innovations in this exciting interdisciplinary field.”

Conventional water-treatment technologies include chemicals, which can produce toxic byproducts, and ultraviolet light, which takes a relatively long time to disinfect and requires a source of electricity.

The new disinfectant developed at Stanford is a harmless metallic powder that works by absorbing both UV and high-energy visible light from the sun. The powder consists of nano-size flakes of aluminum oxide, molybdenum sulfide, copper, and iron oxide.

“We only used a tiny amount of these materials,” said senior author Yi Cui, the Fortinet Founders Professor of MSE and of Energy Science & Engineering in the Stanford Doerr School of Sustainability. “The materials are low cost and fairly abundant. The key innovation is that, when immersed in water, they all function together.”

New nontoxic powder uses sunlight to quickly disinfect contaminated drinking water, Mark Shwartz, Stanford News.

The new composition for fluorine-containing electrolytes promises to maintain high battery charging performance for future electric vehicles even at sub-zero temperatures. (Image by Shutterstock.)

Topics: Battery, Chemistry, Climate Change, Global Warming, Lithium, Materials Science

Scientists developed a new and safer electrolyte for lithium-ion batteries that work as well in sub-zero conditions as it does at room temperature.

Many owners of electric vehicles worry about how effective their batteries will be in very cold weather. Now new battery chemistry may have solved that problem.

In current lithium-ion batteries, the main problem lies in the liquid electrolyte. This key battery component transfers charge-carrying particles called ions between the battery’s two electrodes, causing the battery to charge and discharge. But the liquid begins to freeze at sub-zero temperatures. This condition severely limits the effectiveness of charging electric vehicles in cold regions and seasons.

To address that problem, a team of scientists from the U.S. Department of Energy’s (DOE) Argonne and Lawrence Berkeley national laboratories developed a fluorine-containing electrolyte that performs well even in sub-zero temperatures.

“Our research thus demonstrated how to tailor the atomic structure of electrolyte solvents to design new electrolytes for sub-zero temperatures.” — John Zhang, Argonne group leader.

“Our team not only found an antifreeze electrolyte whose charging performance does not decline at minus 4 degrees Fahrenheit, but we also discovered, at the atomic level, what makes it so effective,” said Zhengcheng ​“John” Zhang, a senior chemist and group leader in Argonne’s Chemical Sciences and Engineering division.

This low-temperature electrolyte shows promise of working for batteries in electric vehicles, as well as in energy storage for electric grids and consumer electronics like computers and phones.

An electric vehicle battery for all seasons, Joseph E. Harmon, Argonne National Labs

The new self-powered thermoelectric generator device uses an ultra-broadband solar absorber (UBSA) to capture sunlight, which heats the generator. Simultaneously, another component called a planar radiative cooling emitter (RCE) cools part of the device by releasing heat. Credit: Haoyuan Cai, Jimei University

Topics: Alternate Energy, Battery, Chemistry, Energy, Materials Science, Thermodynamics

Researchers have developed a new thermoelectric generator (TEG) that can continuously generate electricity using heat from the sun and a radiative element that releases heat into the air. Because it works during the day or night and in cloudy conditions, the new self-powered TEG could provide a reliable power source for small electronic devices such as outdoor sensors.

"Traditional power sources like batteries are limited in capacity and require regular replacement or recharging, which can be inconvenient and unsustainable," said research team leader Jing Liu from Jimei University in China. "Our new TEG design could offer a sustainable and continuous energy solution for small devices, addressing the constraints of traditional power sources like batteries."

TEGs are solid-state devices that use temperature differences to generate electricity without moving parts. In the journal Optics Express, Liu and a multi-institutional team of researchers describe and demonstrate a new TEG that can simultaneously generate the heat and cold necessary to create a temperature difference large enough to generate electricity even when the sun isn't out. The passive power source is made of components that can easily be manufactured.

"The unique design of our self-powered thermoelectric generator allows it to work continuously, no matter the weather," said Liu. "With further development, our TEG has the potential to impact a wide range of applications, from remote sensors to wearable electronics, promoting a more sustainable and eco-friendly approach to powering our daily lives."

New passive device continuously generates electricity during the day or night, Optica/Tech Explore

Credit: CC0 Public Domain

Topics: Applied Physics, Chemistry, Materials Science, Metamaterials, Quantum Mechanics

The behavior of so-called "strange metals" has long puzzled scientists—but a group of researchers at the University of Toronto may be one step closer to understanding these materials.

Electrons are discrete, subatomic particles that flow through wires like molecules of water flowing through a pipe. The flow is known as electricity, and it is harnessed to power and control everything from lightbulbs to the Large Hadron Collider.

In quantum matter, by contrast, electrons don't behave as they do in normal materials. They are much stronger, and the four fundamental properties of electrons—charge, spin, orbit, and lattice—become intertwined, resulting in complex states of matter.

"In quantum matter, electrons shed their particle-like character and exhibit strange collective behavior," says condensed matter physicist Arun Paramekanti, a professor in the U of T's Department of Physics in the Faculty of Arts & Science. "These materials are known as non-Fermi liquids, in which the simple rules break down."

Now, three researchers from the university's Department of Physics and Centre for Quantum Information & Quantum Control (CQIQC) have developed a theoretical model describing the interactions between subatomic particles in non-Fermi liquids. The framework expands on existing models and will help researchers understand the behavior of these "strange metals."

Their research was published in the journal Proceedings of the National Academy of Sciences (PNAS). The lead author is physics Ph.D. student Andrew Hardy, with co-authors Paramekanti and post-doctoral researcher Arijit Haldar.

"We know that the flow of a complex fluid like blood through arteries is much harder to understand than water through pipes," says Paramekanti. "Similarly, the flow of electrons in non-Fermi liquids is much harder to study than that in simple metals."

Hardy adds, "What we've done is construct a model, a tool, to study non-Fermi liquid behavior. And specifically, to deal with what happens when there is symmetry breaking, when there is a phase transition into a new type of system."

"Symmetry breaking" is the term used to describe a fundamental process found in all of nature. Symmetry breaks when a system—whether a droplet of water or the entire universe—loses its symmetry and homogeneity and becomes more complex.

Researchers develop new insight into the enigmatic realm of 'strange metals', Chris Sasaki, University of Toronto, Phys.org

Photo: Getty Images

Topics: Battery, Chemistry, Climate Change, Economics, Global Warming

Welcome back to The Green Era, a weekly newsletter bringing you the news and trends in the world of sustainability. Click subscribe above to be notified of future editions.

The shift to renewable energy has caused consternation over the fate of workers in the fossil fuel industry. Those same concerns are hitting the automotive sector as U.S. demand for electric vehicles grows.

EVs require not just new assembly lines and parts but also factories to build the batteries that power them. The president of one of the biggest unions called the transition the largest in the industry’s history.

The automotive sector and its workers are not new to factory closures. The Great Recession brought the big three automakers to their knees, forcing the federal government to bail them out, leaving cities like Detroit and large swaths of the midwest with car workers out of a job.

This time could be different. Many factories are being converted and are investing in retraining their workers. The batteries and charging infrastructure required present another opportunity. Ford, General Motors, and Volkswagen are all building new battery manufacturing plants or expanding existing ones in Tennessee.

The EV transition is changing workers’ skills and state economies, Jordyn Dahl, LinkedIn

Credit: Pixabay/CC0 Public Domain

Topics: Chemistry, Computer Modeling, Environment, Materials Science

In an advance, they consider a breakthrough in computational chemistry research. University of Wisconsin–Madison chemical engineers have developed a model of how catalytic reactions work at the atomic scale. This understanding could allow engineers and chemists to develop more efficient catalysts and tune industrial processes—potentially with enormous energy savings, given that 90% of the products we encounter in our lives are produced, at least partially, via catalysis.

Catalyst materials accelerate chemical reactions without undergoing changes themselves. They are critical for refining petroleum products and for manufacturing pharmaceuticals, plastics, food additives, fertilizers, green fuels, industrial chemicals, and much more.

Scientists and engineers have spent decades fine-tuning catalytic reactions—yet because it's currently impossible to directly observe those reactions at the extreme temperatures and pressures often involved in industrial-scale catalysis, they haven't known exactly what is taking place on the nano and atomic scales. This new research helps unravel that mystery with potentially major ramifications for the industry.

In fact, just three catalytic reactions—steam-methane reforming to produce hydrogen, ammonia synthesis to produce fertilizer, and methanol synthesis—use close to 10% of the world's energy.

"If you decrease the temperatures at which you have to run these reactions by only a few degrees, there will be an enormous decrease in the energy demand that we face as humanity today," says Manos Mavrikakis, a professor of chemical and biological engineering at UW–Madison who led the research. "By decreasing the energy needed to run all these processes, you are also decreasing their environmental footprint."

New atomic-scale understanding of catalysis could unlock massive energy savings, Jason Daley, University of Madison-Wisconson

Researchers detected a surprising rise in levels of chlorofluorocarbons between 2010 and 2020 using a monitoring network that includes the Jungfraujoch research station in Switzerland. Credit: Shutterstock

 Topics: Chemistry, Civilization, Climate Change, Environment, Global Warming

From my resume: "I eliminated ozone-depleting materials using Failure Mode and Effects Analysis (FMEA) and Taguchi Methods of Quality Engineering - using an L16 Orthogonal Array - in the Poly Silicon etch substituting out CFCs in manufacturing processes." How I did it: I substituted our CFC with Sulfur Hexafluoride and Nitrogen (SF6/N2). On the negative photoresist product, the CFC over-etch was 50 seconds. For the positive photoresist, CFC had a 25-second process. I was able to reduce each product line to two seconds, increasing throughput, and the process increased die yields. It is possible to balance the positive impact of product improvement and the environment. I did it in the 90s, so the following report is disappointing.

*****

The Montreal Protocol, which banned most uses of ozone-destroying chemicals known as chlorofluorocarbons (CFCs) and called for their global phase-out by 2010, has been a great success story: Earth’s ozone layer is projected to recover by the 2060s.

So atmospheric chemists were surprised to see a troubling signal in recent data. They found that the levels of five CFCs rose rapidly in the atmosphere from 2010 to 2020. Their results are published today in Nature Geoscience¹.

“This shouldn’t be happening,” says Martin Vollmer, an atmospheric chemist at the Swiss Federal Laboratories for Materials Science and Technology in Dübendorf, who helped to analyze data from an international network of CFC monitors. “We expect the opposite trend. We expect them to slowly go down.”

At current levels, these CFCs do not pose much threat to the ozone layer’s healing, said Luke Western, a chemist at the University of Bristol, UK, at an online press conference on 30 March. CFCs, once used as refrigerants and aerosols, can persist in the atmosphere for hundreds of years. Given that they are potent greenhouse gases, eliminating emissions of these CFCs will also have a positive impact on Earth’s climate. The collective annual warming effect of these five chemicals on the planet is equivalent to the emissions produced by a small country like Switzerland.

It’s highly likely that manufacturing plants are accidentally releasing three of the chemicals — CFC-113a, CFC-114a, and CFC-115 — while producing replacements for CFCs. When CFCs were phased out, hydrofluorocarbons (HFCs) were brought in as substitutes. But CFCs can crop up as unintended by-products during HFC manufacture. This accidental production is discouraged by the Montreal Protocol but not prohibited by it.

‘This shouldn’t be happening: levels of banned CFCs rising, Katherine Bourzac, Nature

Divine light The Dean of Gloucester Cathedral, Stephen Lake, blesses the cathedral’s solar panels after the solar-energy firm MyPower installed them in November 2016. The array of PV panels generates just over 25% of the building’s electricity. (Courtesy: MyPower)

Topics: Alternate Energy, Applied Physics, Battery, Chemistry, Economics, Solar Power

With energy bills on the rise, plenty of people are interested in ditching the fossil fuels currently used to heat most UK homes. The question is how to make it happen, as Margaret Harris explains.

Deep beneath the flagstones of the medieval Bath Abbey church, a modern marvel with an ancient twist is silently making its presence felt. Completed in March 2021, the abbey’s heating system combines underfloor pipes with heat exchangers located seven meters below the surface. There, a drain built nearly 2000 years ago carries 1.1 million liters of 40 °C water every day from a natural hot spring into a complex of ancient Roman baths.

By tapping into this flow of warm water, the system provides enough energy to heat not only the abbey but also an adjacent row of Georgian cottages used for offices. No wonder the abbey’s rector praised it as “a sustainable solution for heating our beautiful historic church.”

But that wasn’t all. Once efforts to decarbonize the abbey’s heating were underway, officials in the £19.4m Bath Abbey Footprint project turned their attention to the building’s electricity. Like most churches, the abbey runs from east to west, giving its roof an extensive south-facing aspect. At the UK’s northerly latitudes, such roofs are bathed in sunlight for much of the day, making them ideal for solar photovoltaic (PV) panels. Gloucester Cathedral – an hour’s drive north of Bath – has already taken advantage of this favorable orientation, becoming – in 2016 – the UK’s first major ancient cathedral to have solar panels installed on its roof.

To find out if a similar set-up might be suitable at Bath Abbey, the Footprint project worked with Ph.D. students in the University of Bath-led Centre for Doctoral Training (CDT) in New and Sustainable Photovoltaics. In a feasibility study published in Energy Science & Engineering (2022 10 892), the students calculated that a well-designed array of PV panels could supply 35.7% of the abbey’s electricity, plus 4.6% that could be sold back to the grid on days when a surplus was generated. The array would pay for itself within about 13 years and generate a total profit of £139,000 ± £12,000 over its 25-year lifetime.

Home, green home: scientific solutions for cutting carbon and (maybe) saving money, Margaret Harris, Physics World

How it works: illustration of the quantum twisting microscope in action. Electrons tunnel from the probe (inverted pyramid at the top) to the sample (bottom) in several places at once (green vertical lines) in a quantum-coherent manner. (Courtesy: Weizmann Institute of Science)

Topics: Chemistry, Entanglement, Materials Science, Nanotechnology, Quantum Mechanics

When the scanning tunneling microscope debuted in the 1980s, the result was an explosion in nanotechnology and quantum-device research. Since then, other types of scanning probe microscopes have been developed, and together they have helped researchers flesh out theories of electron transport. But these techniques probe electrons at a single point, thereby observing them as particles and only seeing their wave nature indirectly. Now, researchers at the Weizmann Institute of Science in Israel have built a new scanning probe – the quantum twisting microscope – that detects the quantum wave characteristics of electrons directly.

“It’s effectively a scanning probe tip with an interferometer at its apex,” says Shahal Ilani, the team leader. The researchers overlay a scanning probe tip with ultrathin graphite, hexagonal boron nitride, and a van der Waals crystal such as graphene, which conveniently flopped over the tip like a tent with a flat top about 200 nm across. The flat end is key to the device’s interferometer function.  Instead of an electron tunneling between one point in the sample and the tip, the electron wave function can tunnel across multiple points simultaneously.

“Quite surprisingly, we found that the flat end naturally pivots so that it is always parallel with the sample,” says John Birkbeck, the corresponding author of a paper describing this work. This is fortunate because any tilt would alter the tunneling distance and hence strength from one side of the plateau to the other. “It is the interference of these tunneling paths, as identified in the measured current, that gives the device its unique quantum-wave probing function,” says Birkbeck.

Scanning probe with a twist observes the electron’s wavelike behavior, Anna Demming, Physics World

Credit: VTT Technical Research Centre of Finland

Topics: Biology, Biotechnology, Chemistry, Materials Science, Mechanical Engineering

A research group from VTT Technical Research Center of Finland has unlocked the secret behind the extraordinary mechanical properties and ultra-light weight of certain fungi. The complex architectural design of mushrooms could be mimicked and used to create new materials to replace plastics. The research results were published on February 22, 2023, in Science Advances.

VTT's research shows for the first time the complex structural, chemical, and mechanical features adapted throughout the course of evolution by Hoof mushroom (Fomes fomentarius). These features interplay synergistically to create a completely new class of high-performance materials.

Research findings can be used as a source of inspiration to grow from the bottom up the next generation of mechanically robust and lightweight, sustainable materials for various applications under laboratory conditions. These include impact-resistant implants, sports equipment, body armor, and exoskeletons for aircraft, electronics, or windshield surface coatings.

Mushrooms could help replace plastics in new high-performance ultra-light materials, VTT Technical Research Centre of Finland, Phys.org.

Credit: Nicoletta Barolini

Topics: Chemistry, Graphene, Materials Science, Modern Physics, Nanotechnology

Graphullerene, an atom-thin material made of linked fullerene subunits, gives scientists a new form of modular carbon to play with.

Carbon, in its myriad forms, has long captivated the scientific community. Besides being the primary component of all organic life on earth, material forms of carbon have earned their fair share of breakthroughs. In 1996, the Nobel Prize in Chemistry went to the discoverers of fullerene, a superatomic symmetrical structure of 60 carbon atoms shaped like a soccer ball; in 2010, researchers working with an ultra-strong, atom-thin version of carbon, known as graphene, won the Nobel Prize in Physics.

Today in work published in Nature, researchers led by Columbia chemists Xavier Roy, Colin Nuckolls, and Michael Steigerwald, with postdoc and first author Elena Meirzadeh have discovered a new version of carbon that sits somewhere in between fullerene and graphene: graphullerene. It’s a new two-dimensional form of carbon made up of layers of linked fullerenes peeled into ultrathin flakes from a larger graphullerite crystal—just like how graphene is peeled from graphite crystals (the same material found in pencils).

“It is amazing to find a new form of carbon,” said Nuckolls. “It also makes you realize that there is a whole family of materials that can be made in a similar way that will have new and unusual properties as a consequence of the information written into the superatomic building blocks.”

Columbia Chemists Discover a New Form of Carbon: Graphene’s “Superatomic” Cousin, Ellen Neff, Quantum.Columbia.edu

Massive subsidies to regain the edge of the US semiconductor industry will not likely succeed unless progress is made in winning the global race of idea flow and monetization.

Topics: Applied Physics, Chemistry, Computer Science, Electrical Engineering, Semiconductor Technology

Intelligent use of subsidies for winning the global idea race is a must for gaining and regaining semiconductor edge.

The US semiconductor industry started with the invention of Bell Labs. Subsequently, it attained supremacy in semiconductor production due to the success of making computers better and cheaper. Notably, the rise of the PC wave made Intel and Silicon Valley seemingly unsinkable technology superpowers. But during the first two decades of the 21^st century, America has lost it. The USA now relies on Asia to import the most advanced chips. Its iconic Intel is now a couple of technology generation behind Asia’s TSMC and Samsung.

Furthermore, China’s aggressive move has added momentum to America’s despair, triggering a chip war. But why has America lost the edge? Why does it rely on TSMC and Samsung to supply the most advanced chips to power iPhones, Data centers, and Weapons? Is it due to Asian Governments’ subsidies? Or is it due to America’s failure to understand dynamics, make prudent decisions and manage technology and innovation?

Invention and rise and fall of US semiconductor supremacy

In 1947, Bell Labs of the USA invented a semiconductor device—the Transistor. Although American companies developed prototypes of Transistor radios and other consumer electronic products, they did not immediately pursue them. But American firms were very fast in using the Transistor to reinvent computers—by changing the vacuum tube technology core. Due to weight advantage, US Airforce and NASA found transistors suitable for onboard computers. Besides, the invention of integrated circuits by Fairchild and Texas instruments accelerated the weight and size reduction of digital logic circuits. Consequentially, the use of semiconductors in building onboard computers kept exponentially growing. Hence, by the end of the 1960s, the US had become a powerhouse in logic circuit semiconductors. But America remained 2^nd to Japan in global production, as Japanese companies were winning the race of consumer electronics by using transistors.

US Semiconductor–from invention, supremacy to despair, Rokon Zaman, The-Waves.org